Synthesis of propargylic fluorides from allenylsilanes

Laurence Carroll; Ma Carmen Pacheco; Ludivine Garcia; Véronique Gouverneur

doi:10.1039/b610013a

Synthesis of propargylic fluorides from allenylsilanes

Laurence Carroll, Ma Carmen Pacheco, Ludivine Garcia, Véronique Gouverneur

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

Original language	English (US)
Pages (from-to)	4113-4115
Number of pages	3
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/b610013a
State	Published - Jan 1 2006
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b610013a

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title = "Synthesis of propargylic fluorides from allenylsilanes",

abstract = "Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.",

author = "Laurence Carroll and Pacheco, {Ma Carmen} and Ludivine Garcia and V{\'e}ronique Gouverneur",

year = "2006",

month = jan,

day = "1",

doi = "10.1039/b610013a",

language = "English (US)",

pages = "4113--4115",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "39",

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T1 - Synthesis of propargylic fluorides from allenylsilanes

AU - Carroll, Laurence

AU - Pacheco, Ma Carmen

AU - Garcia, Ludivine

AU - Gouverneur, Véronique

PY - 2006/1/1

Y1 - 2006/1/1

N2 - Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

AB - Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

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U2 - 10.1039/b610013a

DO - 10.1039/b610013a

M3 - Article

AN - SCOPUS:33749515656

SN - 1359-7345

SP - 4113

EP - 4115

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

Synthesis of propargylic fluorides from allenylsilanes

Abstract

ASJC Scopus subject areas

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