Studies on organic peroxide/N,N-di (2-α-methyl-acryloyloxy propyl) -para-toluidine binary systems

Kunyuan Qiu; Jie Fu; Xinqiu Guo; Xinde Feng

Studies on organic peroxide/N,N-di (2-α-methyl-acryloyloxy propyl) -para-toluidine binary systems

Kunyuan Qiu, Jie Fu, Xinqiu Guo, Xinde Feng

Research output: Contribution to journal › Article › peer-review

Abstract

The polymerization of methyl methacrylate (MMA) initiated by organic peroxide and polymerizable aromatic tertiary amine such as N, N-di (2-α-methylacryloyloxy propyl)-P-toluidine (MP)₂PT binary system has been studied. It was found that the (MP)₂PT promotes MMA polymerization, and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.

Original language	English (US)
Pages (from-to)	188-195
Number of pages	8
Journal	Chinese Journal of Polymer Science (English Edition)
Volume	8
Issue number	2
State	Published - Jan 1 1990
Externally published	Yes

ASJC Scopus subject areas

Chemical Engineering(all)
Organic Chemistry
Polymers and Plastics

Cite this

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title = "Studies on organic peroxide/N,N-di (2-α-methyl-acryloyloxy propyl) -para-toluidine binary systems",

abstract = "The polymerization of methyl methacrylate (MMA) initiated by organic peroxide and polymerizable aromatic tertiary amine such as N, N-di (2-α-methylacryloyloxy propyl)-P-toluidine (MP)2PT binary system has been studied. It was found that the (MP)2PT promotes MMA polymerization, and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.",

author = "Kunyuan Qiu and Jie Fu and Xinqiu Guo and Xinde Feng",

year = "1990",

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AU - Fu, Jie

AU - Guo, Xinqiu

AU - Feng, Xinde

PY - 1990/1/1

Y1 - 1990/1/1

N2 - The polymerization of methyl methacrylate (MMA) initiated by organic peroxide and polymerizable aromatic tertiary amine such as N, N-di (2-α-methylacryloyloxy propyl)-P-toluidine (MP)2PT binary system has been studied. It was found that the (MP)2PT promotes MMA polymerization, and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.

AB - The polymerization of methyl methacrylate (MMA) initiated by organic peroxide and polymerizable aromatic tertiary amine such as N, N-di (2-α-methylacryloyloxy propyl)-P-toluidine (MP)2PT binary system has been studied. It was found that the (MP)2PT promotes MMA polymerization, and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.

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ER -

Studies on organic peroxide/N,N-di (2-α-methyl-acryloyloxy propyl) -para-toluidine binary systems

Abstract

ASJC Scopus subject areas

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