Remote stereocontrol as a synthetic strategy: Diastereoselective annulations on an arene tricarbonylchromium template

Surojit Sur; Sambasivam Ganesh; Vedavati G. Puranik; Amitabha Sarkar

doi:10.1039/a705285e

Remote stereocontrol as a synthetic strategy: Diastereoselective annulations on an arene tricarbonylchromium template

Surojit Sur, Sambasivam Ganesh, Vedavati G. Puranik, Amitabha Sarkar

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Stereoselective annulations on Cr(CO)₃ complexed tetralone and benzosuberone § derivatives have been achieved. Diastereomeric products are shown to be related by an epimerisable chiral centre. An unusually facile de-ethoxycarbonylation has been observed.

Original language	English (US)
Pages (from-to)	977-982
Number of pages	6
Journal	Journal of the Chemical Society - Perkin Transactions 1
Issue number	5
DOIs	https://doi.org/10.1039/a705285e
State	Published - Mar 7 1998
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Remote stereocontrol as a synthetic strategy: Diastereoselective annulations on an arene tricarbonylchromium template",

abstract = "Stereoselective annulations on Cr(CO)3 complexed tetralone and benzosuberone § derivatives have been achieved. Diastereomeric products are shown to be related by an epimerisable chiral centre. An unusually facile de-ethoxycarbonylation has been observed.",

author = "Surojit Sur and Sambasivam Ganesh and Puranik, {Vedavati G.} and Amitabha Sarkar",

year = "1998",

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AU - Sur, Surojit

AU - Ganesh, Sambasivam

AU - Puranik, Vedavati G.

AU - Sarkar, Amitabha

PY - 1998/3/7

Y1 - 1998/3/7

N2 - Stereoselective annulations on Cr(CO)3 complexed tetralone and benzosuberone § derivatives have been achieved. Diastereomeric products are shown to be related by an epimerisable chiral centre. An unusually facile de-ethoxycarbonylation has been observed.

AB - Stereoselective annulations on Cr(CO)3 complexed tetralone and benzosuberone § derivatives have been achieved. Diastereomeric products are shown to be related by an epimerisable chiral centre. An unusually facile de-ethoxycarbonylation has been observed.

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Remote stereocontrol as a synthetic strategy: Diastereoselective annulations on an arene tricarbonylchromium template

Abstract

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