Abstract
Curvy cubes: Palladium concave nanocubes enclosed by high-index {730} facets were obtained in high purity by controlling the overgrowth of Pd cubic seeds (see scheme). The concave nanocubes showed a much higher catalytic activity than the conventional Pd nanocubes enclosed by {100} facets for both electro-oxidation of formic acid and Suzuki coupling reaction.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 7850-7854 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 50 |
| Issue number | 34 |
| DOIs | |
| State | Published - Aug 16 2011 |
| Externally published | Yes |
Keywords
- crystal growth
- high-index facets
- kinetic control
- nanoparticles
- palladium
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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