Local ordering in asymmetric chain fluids

Daniel R. Kuespert; Marc D. Donohue

doi:10.1063/1.464357

Local ordering in asymmetric chain fluids

Daniel R. Kuespert
, Marc D. Donohue

Research output: Contribution to journal › Article › peer-review

Abstract

A thermodynamic study of local ordering in amphiphilic chain fluids based on the sphere-and-bond formalism of Kuespert and Donohue [Langmuir 9, 431 (1993)] is presented using the Flory equation for entropy of mixing and the mean-field approximation for fluid energy. After introducing general equations, a model of an amphiphile chain dissolved in a monomeric solvent is derived and its bulk and microphase equilibria are investigated.

Original language	English (US)
Pages (from-to)	9782-9789
Number of pages	8
Journal	The Journal of Chemical Physics
Volume	98
Issue number	12
DOIs	https://doi.org/10.1063/1.464357
State	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.464357

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abstract = "A thermodynamic study of local ordering in amphiphilic chain fluids based on the sphere-and-bond formalism of Kuespert and Donohue [Langmuir 9, 431 (1993)] is presented using the Flory equation for entropy of mixing and the mean-field approximation for fluid energy. After introducing general equations, a model of an amphiphile chain dissolved in a monomeric solvent is derived and its bulk and microphase equilibria are investigated.",

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Local ordering in asymmetric chain fluids

Abstract

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