Enhancement of co2 selectivity in a pillared pcu mom platform through pillar substitution

Patrick Nugent; Vanessah Rhodus; Tony Pham; Brant Tudor; Katherine Forrest; Lukasz Wojtas; Brian Space; Michael Zaworotko

doi:10.1039/c3cc37695h

Enhancement of co₂ selectivity in a pillared pcu mom platform through pillar substitution

Patrick Nugent, Vanessah Rhodus, Tony Pham, Brant Tudor, Katherine Forrest, Lukasz Wojtas, Brian Space, Michael Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)₂(SiF₆)]_n, has afforded the first crystallographically characterized porous materials based upon TiF₆²⁻ and SnF₆²⁻ anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO₂ vs. CH₄ and N₂.

Original language	English (US)
Pages (from-to)	1606-1608
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	16
DOIs	https://doi.org/10.1039/c3cc37695h
State	Published - Jan 29 2013
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/c3cc37695h

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abstract = "Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N2.",

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AU - Nugent, Patrick

AU - Rhodus, Vanessah

AU - Pham, Tony

AU - Tudor, Brant

AU - Forrest, Katherine

AU - Wojtas, Lukasz

AU - Space, Brian

AU - Zaworotko, Michael

PY - 2013/1/29

Y1 - 2013/1/29

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AB - Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N2.

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Enhancement of co₂ selectivity in a pillared pcu mom platform through pillar substitution

Abstract

ASJC Scopus subject areas

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