Efficient preparation of glycoclusters from silsesquioxanes

Yongjun Gao; Atsuko Eguchi; Kazuaki Kakehi; Yuan C. Lee

doi:10.1021/ol040043a

Efficient preparation of glycoclusters from silsesquioxanes

Yongjun Gao, Atsuko Eguchi, Kazuaki Kakehi, Yuan C. Lee

School of Medicine

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

(Chemical Equation Presented) A new type of glycocluster based on polyhedral oligosilsesquioxanes (POSS) has been efficiently prepared from unprotected mannoside and lactoside employing a convergent approach of thiol-radical addition reaction. The versatility of this approach was demonstrated by functionalization of mannosides and lactosides of different-length spacers.

Original language	English (US)
Pages (from-to)	3457-3460
Number of pages	4
Journal	Organic Letters
Volume	6
Issue number	20
DOIs	https://doi.org/10.1021/ol040043a
State	Published - Sep 30 2004

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol040043a

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title = "Efficient preparation of glycoclusters from silsesquioxanes",

abstract = "(Chemical Equation Presented) A new type of glycocluster based on polyhedral oligosilsesquioxanes (POSS) has been efficiently prepared from unprotected mannoside and lactoside employing a convergent approach of thiol-radical addition reaction. The versatility of this approach was demonstrated by functionalization of mannosides and lactosides of different-length spacers.",

author = "Yongjun Gao and Atsuko Eguchi and Kazuaki Kakehi and Lee, {Yuan C.}",

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AU - Gao, Yongjun

AU - Eguchi, Atsuko

AU - Kakehi, Kazuaki

AU - Lee, Yuan C.

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Y1 - 2004/9/30

N2 - (Chemical Equation Presented) A new type of glycocluster based on polyhedral oligosilsesquioxanes (POSS) has been efficiently prepared from unprotected mannoside and lactoside employing a convergent approach of thiol-radical addition reaction. The versatility of this approach was demonstrated by functionalization of mannosides and lactosides of different-length spacers.

AB - (Chemical Equation Presented) A new type of glycocluster based on polyhedral oligosilsesquioxanes (POSS) has been efficiently prepared from unprotected mannoside and lactoside employing a convergent approach of thiol-radical addition reaction. The versatility of this approach was demonstrated by functionalization of mannosides and lactosides of different-length spacers.

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Efficient preparation of glycoclusters from silsesquioxanes

Abstract

ASJC Scopus subject areas

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