Design and regioselective synthesis of (2-Bromo-2-alkoxycarbonyl)ethyl acrylates as inimers for hyperbranched (Co)polyacrylates

Coleen Pugh; Bindu Raveendra; Anirudha Singh; Reichel Samuel; Guillermina Garcia

doi:10.1055/s-0030-1258497

Design and regioselective synthesis of (2-Bromo-2-alkoxycarbonyl)ethyl acrylates as inimers for hyperbranched (Co)polyacrylates

Coleen Pugh, Bindu Raveendra, Anirudha Singh, Reichel Samuel, Guillermina Garcia

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A route based on deaminohalogenation of serine is established to synthesize bromoinimers that can be homopolymerized to produce hyperbranched polyacrylates that are true architectural analogues of linear polyacrylates; that is, an ester group is attached to every other carbon along the polymer backbone, and each repeat unit contains a free ester side chain.

Original language	English (US)
Pages (from-to)	1947-1950
Number of pages	4
Journal	Synlett
Issue number	13
DOIs	https://doi.org/10.1055/s-0030-1258497
State	Published - 2010
Externally published	Yes

Keywords

Acrylates
Activated ester
Deaminohalogenation
Inimers
Regioselective

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0030-1258497

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title = "Design and regioselective synthesis of (2-Bromo-2-alkoxycarbonyl)ethyl acrylates as inimers for hyperbranched (Co)polyacrylates",

abstract = "A route based on deaminohalogenation of serine is established to synthesize bromoinimers that can be homopolymerized to produce hyperbranched polyacrylates that are true architectural analogues of linear polyacrylates; that is, an ester group is attached to every other carbon along the polymer backbone, and each repeat unit contains a free ester side chain.",

keywords = "Acrylates, Activated ester, Deaminohalogenation, Inimers, Regioselective",

author = "Coleen Pugh and Bindu Raveendra and Anirudha Singh and Reichel Samuel and Guillermina Garcia",

year = "2010",

doi = "10.1055/s-0030-1258497",

language = "English (US)",

pages = "1947--1950",

journal = "Synlett",

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T1 - Design and regioselective synthesis of (2-Bromo-2-alkoxycarbonyl)ethyl acrylates as inimers for hyperbranched (Co)polyacrylates

AU - Pugh, Coleen

AU - Raveendra, Bindu

AU - Singh, Anirudha

AU - Samuel, Reichel

AU - Garcia, Guillermina

PY - 2010

Y1 - 2010

N2 - A route based on deaminohalogenation of serine is established to synthesize bromoinimers that can be homopolymerized to produce hyperbranched polyacrylates that are true architectural analogues of linear polyacrylates; that is, an ester group is attached to every other carbon along the polymer backbone, and each repeat unit contains a free ester side chain.

AB - A route based on deaminohalogenation of serine is established to synthesize bromoinimers that can be homopolymerized to produce hyperbranched polyacrylates that are true architectural analogues of linear polyacrylates; that is, an ester group is attached to every other carbon along the polymer backbone, and each repeat unit contains a free ester side chain.

KW - Acrylates

KW - Activated ester

KW - Deaminohalogenation

KW - Inimers

KW - Regioselective

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DO - 10.1055/s-0030-1258497

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SN - 0936-5214

SP - 1947

EP - 1950

JO - Synlett

JF - Synlett

IS - 13

ER -

Design and regioselective synthesis of (2-Bromo-2-alkoxycarbonyl)ethyl acrylates as inimers for hyperbranched (Co)polyacrylates

Abstract

Keywords

ASJC Scopus subject areas

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