Carbon CP-MASS NMR and X-ray Crystal Structure of Paramagnetic Lanthanide Acetates

S. Ganapathy, R. G. Bryant, V. P. Chacko, M. C. Etter

Research output: Contribution to journalArticlepeer-review

79 Scopus citations

Abstract

The X-ray crystal structures of praseodymium(III) acetate monohydrate and europium(III) acetate trihydrate have been solved and cross-polarization carbon-13 NMR spectra obtained in the polycrystalline solids. The static and magic angle spinning spectra are compared with diamagnetic acetate spectra. The shifts in the paramagnetic compounds are large, permitting sample heterogeniety to be readily detected. The CP-MASS carbon spectra are assigned by using both relaxation times and dipolar interactions as a guide.

Original languageEnglish (US)
Pages (from-to)3159-3165
Number of pages7
JournalJournal of the American Chemical Society
Volume108
Issue number12
DOIs
StatePublished - Jan 1 1986

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry

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