Abstract
The X-ray crystal structures of praseodymium(III) acetate monohydrate and europium(III) acetate trihydrate have been solved and cross-polarization carbon-13 NMR spectra obtained in the polycrystalline solids. The static and magic angle spinning spectra are compared with diamagnetic acetate spectra. The shifts in the paramagnetic compounds are large, permitting sample heterogeniety to be readily detected. The CP-MASS carbon spectra are assigned by using both relaxation times and dipolar interactions as a guide.
Original language | English (US) |
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Pages (from-to) | 3159-3165 |
Number of pages | 7 |
Journal | Journal of the American Chemical Society |
Volume | 108 |
Issue number | 12 |
DOIs | |
State | Published - Jan 1 1986 |
ASJC Scopus subject areas
- Catalysis
- General Chemistry
- Biochemistry
- Colloid and Surface Chemistry