An examination of π-facial selectivity in the diels-alder reaction of a chiral diene - a synthesis of (+)-5,6,10-tri-(EPI)-Actinobolin.

Alan P. Kozikowski; Thaddeus R. Nieduzak; James P. Springer

doi:10.1016/S0040-4039(00)84109-X

An examination of π-facial selectivity in the diels-alder reaction of a chiral diene - a synthesis of (+)-5,6,10-tri-(EPI)-Actinobolin.

Alan P. Kozikowski, Thaddeus R. Nieduzak, James P. Springer

School of Medicine

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Abstract

The π-facial course of the Diels-Alder reaction of an L-threonine derived silyloxydiene has been examined during the course of a study aimed at the total synthesis of actinobolin/bactobolin.

Original language	English (US)
Pages (from-to)	819-822
Number of pages	4
Journal	Tetrahedron Letters
Volume	27
Issue number	7
DOIs	https://doi.org/10.1016/S0040-4039(00)84109-X
State	Published - 1986

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)84109-X

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title = "An examination of π-facial selectivity in the diels-alder reaction of a chiral diene - a synthesis of (+)-5,6,10-tri-(EPI)-Actinobolin.",

abstract = "The π-facial course of the Diels-Alder reaction of an L-threonine derived silyloxydiene has been examined during the course of a study aimed at the total synthesis of actinobolin/bactobolin.",

author = "Kozikowski, {Alan P.} and Nieduzak, {Thaddeus R.} and Springer, {James P.}",

year = "1986",

doi = "10.1016/S0040-4039(00)84109-X",

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journal = "Tetrahedron Letters",

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AU - Kozikowski, Alan P.

AU - Nieduzak, Thaddeus R.

AU - Springer, James P.

PY - 1986

Y1 - 1986

N2 - The π-facial course of the Diels-Alder reaction of an L-threonine derived silyloxydiene has been examined during the course of a study aimed at the total synthesis of actinobolin/bactobolin.

AB - The π-facial course of the Diels-Alder reaction of an L-threonine derived silyloxydiene has been examined during the course of a study aimed at the total synthesis of actinobolin/bactobolin.

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U2 - 10.1016/S0040-4039(00)84109-X

DO - 10.1016/S0040-4039(00)84109-X

M3 - Article

AN - SCOPUS:0022656986

SN - 0040-4039

VL - 27

SP - 819

EP - 822

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 7

ER -

An examination of π-facial selectivity in the diels-alder reaction of a chiral diene - a synthesis of (+)-5,6,10-tri-(EPI)-Actinobolin.

Abstract

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